THE HYPERFINE STRUCTURES OF CUCL AND CUBR IN THEIR GROUND-STATES STUDIED BY MICROWAVE FOURIER-TRANSFORM SPECTROSCOPY
The hyperfine structure of the J = 1 ← 0 rotational transition of CuCl as well as the J = 3 ← 2, 2 ← 1, and 1 ← 0 rotational transitions of CuBr in the v = 0 vibrational level have been investigated using a microwave Fourier transform spectrometer. The molecules were produced by laser ablation of th...
| Main Authors: | , , , , , |
|---|---|
| 格式: | Journal article |
| 语言: | English |
| 出版: |
1993
|
| _version_ | 1826305260996526080 |
|---|---|
| author | Low, R Varberg, T Connelly, J Auty, A Howard, B Brown, J |
| author_facet | Low, R Varberg, T Connelly, J Auty, A Howard, B Brown, J |
| author_sort | Low, R |
| collection | OXFORD |
| description | The hyperfine structure of the J = 1 ← 0 rotational transition of CuCl as well as the J = 3 ← 2, 2 ← 1, and 1 ← 0 rotational transitions of CuBr in the v = 0 vibrational level have been investigated using a microwave Fourier transform spectrometer. The molecules were produced by laser ablation of the copper halide followed by an axial supersonic expansion into a near-semiconfocal Fabry-Perot cavity. The analysis of the hyperfine structure yielded improved values of the rotational and electric quadrupole constants and determined the nuclear spin-rotation constants for the first time. The physical implications of these results are discussed. © 1993 Academic Press. All rights reserved. |
| first_indexed | 2024-03-07T06:30:13Z |
| format | Journal article |
| id | oxford-uuid:f5be1de1-f073-4a2e-a0fd-634b592fbf5d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:30:13Z |
| publishDate | 1993 |
| record_format | dspace |
| spelling | oxford-uuid:f5be1de1-f073-4a2e-a0fd-634b592fbf5d2022-03-27T12:29:31ZTHE HYPERFINE STRUCTURES OF CUCL AND CUBR IN THEIR GROUND-STATES STUDIED BY MICROWAVE FOURIER-TRANSFORM SPECTROSCOPYJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f5be1de1-f073-4a2e-a0fd-634b592fbf5dEnglishSymplectic Elements at Oxford1993Low, RVarberg, TConnelly, JAuty, AHoward, BBrown, JThe hyperfine structure of the J = 1 ← 0 rotational transition of CuCl as well as the J = 3 ← 2, 2 ← 1, and 1 ← 0 rotational transitions of CuBr in the v = 0 vibrational level have been investigated using a microwave Fourier transform spectrometer. The molecules were produced by laser ablation of the copper halide followed by an axial supersonic expansion into a near-semiconfocal Fabry-Perot cavity. The analysis of the hyperfine structure yielded improved values of the rotational and electric quadrupole constants and determined the nuclear spin-rotation constants for the first time. The physical implications of these results are discussed. © 1993 Academic Press. All rights reserved. |
| spellingShingle | Low, R Varberg, T Connelly, J Auty, A Howard, B Brown, J THE HYPERFINE STRUCTURES OF CUCL AND CUBR IN THEIR GROUND-STATES STUDIED BY MICROWAVE FOURIER-TRANSFORM SPECTROSCOPY |
| title | THE HYPERFINE STRUCTURES OF CUCL AND CUBR IN THEIR GROUND-STATES STUDIED BY MICROWAVE FOURIER-TRANSFORM SPECTROSCOPY |
| title_full | THE HYPERFINE STRUCTURES OF CUCL AND CUBR IN THEIR GROUND-STATES STUDIED BY MICROWAVE FOURIER-TRANSFORM SPECTROSCOPY |
| title_fullStr | THE HYPERFINE STRUCTURES OF CUCL AND CUBR IN THEIR GROUND-STATES STUDIED BY MICROWAVE FOURIER-TRANSFORM SPECTROSCOPY |
| title_full_unstemmed | THE HYPERFINE STRUCTURES OF CUCL AND CUBR IN THEIR GROUND-STATES STUDIED BY MICROWAVE FOURIER-TRANSFORM SPECTROSCOPY |
| title_short | THE HYPERFINE STRUCTURES OF CUCL AND CUBR IN THEIR GROUND-STATES STUDIED BY MICROWAVE FOURIER-TRANSFORM SPECTROSCOPY |
| title_sort | hyperfine structures of cucl and cubr in their ground states studied by microwave fourier transform spectroscopy |
| work_keys_str_mv | AT lowr thehyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT varbergt thehyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT connellyj thehyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT autya thehyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT howardb thehyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT brownj thehyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT lowr hyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT varbergt hyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT connellyj hyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT autya hyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT howardb hyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy AT brownj hyperfinestructuresofcuclandcubrintheirgroundstatesstudiedbymicrowavefouriertransformspectroscopy |