Infrared spectroscopy of the nitrogenase MoFe protein under electrochemical control: potential-triggered CO binding
We demonstrate electrochemical control of the nitrogenase MoFe protein, in the absence of Fe protein or ATP, using europium (III/II) polyaminocarboxylate complexes as electron transfer mediators. This allows the potential dependence of proton reduction and inhibitor (CO) binding to the active site F...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Published: |
Royal Society of Chemistry
2016
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