Tafel-Volmer electrode reactions: The influence of electron-transfer kinetics

A typical Tafel-Volmer electrode reaction, embracing a preceding chemisorption step and a following electron transfer, is explored by simulation. Two different electron transfer formalisms, Butler-Volmer and a Marcus-Hush like approach, are utilised in interpreting the potential...

Full description

Bibliographic Details
Main Authors: Lin, C, Batchelor-McAuley, C, Laborda, E, Compton, R
Format: Journal article
Published: American Chemical Society 2015