2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides.
[reaction: see text] Reaction of hindered lithium amides with readily available (enantiopure) terminal epoxides gives 2-ene-1,4-diols via carbenoid dimerization of the corresponding alpha-lithiated epoxides. D-Mannitol and D-iditol were synthesized using this method in three steps from (S)-tritylgly...
| Glavni autori: | , , |
|---|---|
| Format: | Journal article |
| Jezik: | English |
| Izdano: |
2005
|