2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides.
[reaction: see text] Reaction of hindered lithium amides with readily available (enantiopure) terminal epoxides gives 2-ene-1,4-diols via carbenoid dimerization of the corresponding alpha-lithiated epoxides. D-Mannitol and D-iditol were synthesized using this method in three steps from (S)-tritylgly...
| Päätekijät: | , , |
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| Aineistotyyppi: | Journal article |
| Kieli: | English |
| Julkaistu: |
2005
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| _version_ | 1826305698623913984 |
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| author | Hodgson, D Bray, C Kindon, N |
| author_facet | Hodgson, D Bray, C Kindon, N |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | [reaction: see text] Reaction of hindered lithium amides with readily available (enantiopure) terminal epoxides gives 2-ene-1,4-diols via carbenoid dimerization of the corresponding alpha-lithiated epoxides. D-Mannitol and D-iditol were synthesized using this method in three steps from (S)-tritylglycidyl ether. |
| first_indexed | 2024-03-07T06:36:47Z |
| format | Journal article |
| id | oxford-uuid:f7ed83c3-ad81-433e-9896-ea5caf3bf19a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:36:47Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:f7ed83c3-ad81-433e-9896-ea5caf3bf19a2022-03-27T12:46:23Z2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f7ed83c3-ad81-433e-9896-ea5caf3bf19aEnglishSymplectic Elements at Oxford2005Hodgson, DBray, CKindon, N[reaction: see text] Reaction of hindered lithium amides with readily available (enantiopure) terminal epoxides gives 2-ene-1,4-diols via carbenoid dimerization of the corresponding alpha-lithiated epoxides. D-Mannitol and D-iditol were synthesized using this method in three steps from (S)-tritylglycidyl ether. |
| spellingShingle | Hodgson, D Bray, C Kindon, N 2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides. |
| title | 2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides. |
| title_full | 2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides. |
| title_fullStr | 2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides. |
| title_full_unstemmed | 2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides. |
| title_short | 2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides. |
| title_sort | 2 ene 1 4 diols by dimerization of terminal epoxides using hindered lithium amides |
| work_keys_str_mv | AT hodgsond 2ene14diolsbydimerizationofterminalepoxidesusinghinderedlithiumamides AT brayc 2ene14diolsbydimerizationofterminalepoxidesusinghinderedlithiumamides AT kindonn 2ene14diolsbydimerizationofterminalepoxidesusinghinderedlithiumamides |