The Pentynoate Ligand as a Building Block for Multimetallic Systems
The complexes [RuRCl(CO)(BTD)(PPh3)2] (R = CH=CHtBu, CH=CHC6H4Me-4, CH=CHC5H4FeC 5H5; BTD = 2,1,3-benzothiadiazole) and [Ru{C(C≡CPh)=CHPh}(CO)(PPh3)2] reacted with pentynoic acid to yield the same complex, [RuCl(O2CCH 2CH2C≡CH)(CO)(PPh3)2], through cleavage of the vinyl ligand. In contrast, the prod...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Wiley
2014
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