Taming nonclassical carbocations to control small ring reactivity

Prediction of the outcome of ring opening of small organic rings under cationic conditions can be challenging due to the intermediacy of nonclassical carbocations. For example, the solvolysis of cyclobutyl or cyclopropylmethyl derivatives generates up to four products on nucleophilic capture or elim...

詳細記述

書誌詳細
主要な著者: McNamee, RE, Frank, N, Christensen, KE, Duarte, F, Anderson, EA
フォーマット: Journal article
言語:English
出版事項: American Association for the Advancement of Science 2024