Taming nonclassical carbocations to control small ring reactivity

Prediction of the outcome of ring opening of small organic rings under cationic conditions can be challenging due to the intermediacy of nonclassical carbocations. For example, the solvolysis of cyclobutyl or cyclopropylmethyl derivatives generates up to four products on nucleophilic capture or elim...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: McNamee, RE, Frank, N, Christensen, KE, Duarte, F, Anderson, EA
التنسيق: Journal article
اللغة:English
منشور في: American Association for the Advancement of Science 2024