Very rapid, cooperative two-electron/two-proton redox reactions of [3Fe-4S] clusters: Detection and analysis by protein-film voltammetry
The 'hyper-reduced' [3Fe-4S]2- cluster (consisting formally of three Fe(II) atoms and four sulfides (S2-)) possesses a remarkable capability for very rapid and reversible two-electron/two-proton oxidation (E(o') > -650 mv below pH 7) that is strongly suggestive of disulfide-bas...
| Main Authors: | , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
1998
|