On the mechanism of d-f energy transfer in RuII/LnIII and OsII/LnIII dyads: Dexter-type energy transfer over a distance of 20 A.

On the mechanism of d-f energy transfer in RuII/LnIII and OsII/LnIII dyads: Dexter-type energy transfer over a distance of 20 A.

We have used time-resolved luminescence methods to study rates of photoinduced energy transfer (PEnT) from [M(bipy)3]2+ (M=Ru, Os) chromophores to Ln(III) ions with low-energy f-f states (Ln=Yb, Nd, Er) in d-f dyads in which the metal fragments are separated by a saturated -CH2CH2- spacer, a p-C6H4...

Ausführliche Beschreibung

Bibliographische Detailangaben
Hauptverfasser:	Lazarides, T, Sykes, D, Faulkner, S, Barbieri, A, Ward, MD
Format:	Journal article
Sprache:	English
Veröffentlicht:	2008

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