Topotactic oxidative and reductive control of the structures and properties of layered manganese oxychalcogenides.

Topotactic modification, by both oxidation and reduction, of the composition, structures, and magnetic properties of the layered oxychalcogenides Sr4Mn3O7.5Cu2Ch2 (Ch=S, Se) is described. These Mn3+ compounds are composed of alternating perovskite-type strontium manganese oxide slabs separated by an...

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Bibliographic Details
Main Authors: Hyett, G, Barrier, N, Clarke, S, Hadermann, J
Format: Journal article
Language:English
Published: 2007