Cyclopentadienyl titanium imido compounds and their ethylene polymerization capability: Control of molecular weight distributions by imido N-substituents
Reaction of the previously reported Cp*Ti(NtBu)Cl(py) (1) with bulky ortfzo-substituted anilines ArNH2 afforded the corresponding aryl imido derivatives Cp*Ti(NAr)Cl(py) (Ar = 2,6-C 6H3iPr2 (2), 2,6-C6H 3Br2 (3), 2-C6H41Bu (4), and 2-C6H4iPr (5)). Reaction of 2 with B(C 6F5)3 in C6D6 or heating in v...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2007
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