Sequential reduction of high hydride count octahedral rhodium clusters [Rh6(PR3)6H12][BArF4]2: redox-switchable hydrogen storage.
Cyclic voltammetry on the octahedral rhodium clusters with 12 bridging hydride ligands, [Rh6(PR3)6H12][BArF4]2 (R = Cy Cy-[H12]2+, R = iPr iPr-[H12]2+; [BArF4]- = [B{C6H3(CF3)2}4]-) reveals four potentially accessible redox states: [Rh6(PR3)6H12]0/1+/2+/3+. Chemical oxidation did not produce stable...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2007
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