A short and efficient synthesis of neodysiherbaine A by using catalytic oxidative cyclization.
To the point: The synthesis of the title compound was achieved with 24 overall yield through a sequence that has just seven linear steps (see scheme). Key points are the facial selectivity displayed by an oxocarbenium ion derived from a ribopyranose system and an osmium-catalyzed oxidative cyclizati...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2011
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