Synthesis and reactivity of α‐cumyl bromodifluoromethanesulfenate: application to the radiosynthesis of [18F]arylSCF3

Synthesis and reactivity of α‐cumyl bromodifluoromethanesulfenate: application to the radiosynthesis of [18F]arylSCF3

A highly reactive electrophilic bromodifluoromethylthiolating reagent, α‐cumyl bromodifluoro‐methanesulfenate 1, was prepared to allow for direct bromodifluoromethylthiolation of aryl boron reagents. This coupling reaction takes place under copper catalysis, and affords a large range of bromodifluor...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awduron:	Wu, J, Zhao, Q, Wilson, TC, Verhoog, S, Gouverneur, V, Lu, L, Shen, Q
Fformat:	Journal article
Iaith:	English
Cyhoeddwyd:	Wiley 2019

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