Dehydrogenative boron homocoupling of an amine-borane.

A meeting of borons: The homocoupling of a B-B bond in an amine-borane is reported to give a diborane coordinated to a RhI metal center (see picture; C gray/black, O red, P blue, B green, N orange). The pathway for the occurrence of this reaction was also studied using density functional theory to c...

Descrizione completa

Dettagli Bibliografici
Autori principali: Johnson, H, McMullin, C, Pike, S, Macgregor, SA, Weller, A
Natura: Journal article
Lingua:English
Pubblicazione: 2013