Dehydrogenative boron homocoupling of an amine-borane.
A meeting of borons: The homocoupling of a B-B bond in an amine-borane is reported to give a diborane coordinated to a RhI metal center (see picture; C gray/black, O red, P blue, B green, N orange). The pathway for the occurrence of this reaction was also studied using density functional theory to c...
| Main Authors: | , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2013
|
| _version_ | 1797105746704334848 |
|---|---|
| author | Johnson, H McMullin, C Pike, S Macgregor, SA Weller, A |
| author_facet | Johnson, H McMullin, C Pike, S Macgregor, SA Weller, A |
| author_sort | Johnson, H |
| collection | OXFORD |
| description | A meeting of borons: The homocoupling of a B-B bond in an amine-borane is reported to give a diborane coordinated to a RhI metal center (see picture; C gray/black, O red, P blue, B green, N orange). The pathway for the occurrence of this reaction was also studied using density functional theory to calculate the free energies of each intermediate. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| first_indexed | 2024-03-07T06:51:46Z |
| format | Journal article |
| id | oxford-uuid:fccd6551-cef5-40a5-8ffa-ac5a04e08abe |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:51:46Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:fccd6551-cef5-40a5-8ffa-ac5a04e08abe2022-03-27T13:23:43ZDehydrogenative boron homocoupling of an amine-borane.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fccd6551-cef5-40a5-8ffa-ac5a04e08abeEnglishSymplectic Elements at Oxford2013Johnson, HMcMullin, CPike, SMacgregor, SAWeller, AA meeting of borons: The homocoupling of a B-B bond in an amine-borane is reported to give a diborane coordinated to a RhI metal center (see picture; C gray/black, O red, P blue, B green, N orange). The pathway for the occurrence of this reaction was also studied using density functional theory to calculate the free energies of each intermediate. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| spellingShingle | Johnson, H McMullin, C Pike, S Macgregor, SA Weller, A Dehydrogenative boron homocoupling of an amine-borane. |
| title | Dehydrogenative boron homocoupling of an amine-borane. |
| title_full | Dehydrogenative boron homocoupling of an amine-borane. |
| title_fullStr | Dehydrogenative boron homocoupling of an amine-borane. |
| title_full_unstemmed | Dehydrogenative boron homocoupling of an amine-borane. |
| title_short | Dehydrogenative boron homocoupling of an amine-borane. |
| title_sort | dehydrogenative boron homocoupling of an amine borane |
| work_keys_str_mv | AT johnsonh dehydrogenativeboronhomocouplingofanamineborane AT mcmullinc dehydrogenativeboronhomocouplingofanamineborane AT pikes dehydrogenativeboronhomocouplingofanamineborane AT macgregorsa dehydrogenativeboronhomocouplingofanamineborane AT wellera dehydrogenativeboronhomocouplingofanamineborane |