Reactions of (BuC)-Bu-t P with cyclooctatetraene-supported titanium imido complexes

Reaction of the pseudo two-coordinate titanium imido complexes [Ti(N tBu)(COT)] (1; COT = η8-C8H8) and [Ti(NtBu)(COT″)] (2; COT″ = η 8-1,4-C8H6(SiMe3)2) with 2 equiv of tBuC≡P generated the new complexes [Ti{N( tBu)PC(tBu)PC(tBu)}(COT)] (4) and [Ti{N( tBu)PC(tBu)PC(tBu)}(COT″)] (5), respectively. Co...

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Bibliographic Details
Main Authors: Cloke, F, Green, J, Hazari, N, Hitchcock, P, Mountford, P, Nixon, J, Wilson, D
Format: Journal article
Language:English
Published: 2006