APPLICATION OF SCALING THEORY TO VIBRATIONAL-RELAXATION IN LINEAR ANHARMONIC TRIATOMIC-MOLECULES

The energy-corrected-sudden (ECS) scaling theory is extended to vibrational relaxation in the collisions of anharmonic linear triatomic molecules with atoms. Application is made to the collisions of He atoms with 12C 16O2, 14C 16O2, and 12C 18O2. By combining the rate constants for the (0110→00°0) t...

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Bibliographic Details
Main Authors: Clary, D, Depristo, A
Format: Journal article
Language:English
Published: 1983