SrFe0.5Ru0.5O2: square-planar Ru2+ in an extended oxide.

Low-temperature topochemical reduction of the cation disordered perovskite phase SrFe(0.5)Ru(0.5)O(3) with CaH(2) yields the infinite layer phase SrFe(0.5)Ru(0.5)O(2). Thermogravimetric and X-ray absorption data confirm the transition metal oxidation states as SrFe(0.5)(2+)Ru(0.5)(2+)O(2); thus, the...

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Autori principali: Denis Romero, F, Burr, S, McGrady, J, Gianolio, D, Cibin, G, Hayward, M
Natura: Journal article
Lingua:English
Pubblicazione: 2013