Crystallinity and Si-H bonding configuration of nc-Si:H films grown by Layer-by-layer (LBL) deposition technique at different RF power

A set of hydrogenated nanocrystalline silicon (nc-Si:H) films prepared in a home built plasma enhanced chemical vapour deposition (PECVD) system using the layer by- layer (LBL) deposition technique have been studied. The 13.56 MHz RF power was varied from 20 to 100 W to study the influence of RF po...

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Main Authors: Tong, G.B., Ab. Ghani, S.M., Abdul Rahman, S.
Format: Conference or Workshop Item
Language:English
Published: 2007
Subjects:
Online Access:http://eprints.um.edu.my/13516/1/0001.pdf
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author Tong, G.B.
Ab. Ghani, S.M.
Abdul Rahman, S.
author_facet Tong, G.B.
Ab. Ghani, S.M.
Abdul Rahman, S.
author_sort Tong, G.B.
collection UM
description A set of hydrogenated nanocrystalline silicon (nc-Si:H) films prepared in a home built plasma enhanced chemical vapour deposition (PECVD) system using the layer by- layer (LBL) deposition technique have been studied. The 13.56 MHz RF power was varied from 20 to 100 W to study the influence of RF power on the structural properties of the nc-Si:H films. The structure of the films was studied by means of X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. Appearance of an XRD peak at diffraction angle of 56.1 0 which correspond to silicon orientation of (311) was observed in all films deposited on c-Si substrate indicating evidence of crystallinity in the films. The crystallite sizes were in the range of 5 to 40 nm as determined using the Scherrer technique. The integrated intensities of absorption bands t 630, 780 - 880 and 2000 - 2090 em:' from FTIR spectrum which corresponded to various Si-H bonding configurations in the films were studied and were related to the presence small clusters of nanocrystallites embedded in an amorphous matrix. Based on the dependence of amplitudes of Si- H vibrational modes on crystallite size and RF power, the properties and the role of hydrogen in nc-Si:H films prepared using the LBL technique were discussed.
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spelling um.eprints-135162015-05-13T08:35:14Z http://eprints.um.edu.my/13516/ Crystallinity and Si-H bonding configuration of nc-Si:H films grown by Layer-by-layer (LBL) deposition technique at different RF power Tong, G.B. Ab. Ghani, S.M. Abdul Rahman, S. T Technology (General) A set of hydrogenated nanocrystalline silicon (nc-Si:H) films prepared in a home built plasma enhanced chemical vapour deposition (PECVD) system using the layer by- layer (LBL) deposition technique have been studied. The 13.56 MHz RF power was varied from 20 to 100 W to study the influence of RF power on the structural properties of the nc-Si:H films. The structure of the films was studied by means of X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. Appearance of an XRD peak at diffraction angle of 56.1 0 which correspond to silicon orientation of (311) was observed in all films deposited on c-Si substrate indicating evidence of crystallinity in the films. The crystallite sizes were in the range of 5 to 40 nm as determined using the Scherrer technique. The integrated intensities of absorption bands t 630, 780 - 880 and 2000 - 2090 em:' from FTIR spectrum which corresponded to various Si-H bonding configurations in the films were studied and were related to the presence small clusters of nanocrystallites embedded in an amorphous matrix. Based on the dependence of amplitudes of Si- H vibrational modes on crystallite size and RF power, the properties and the role of hydrogen in nc-Si:H films prepared using the LBL technique were discussed. 2007-06 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.um.edu.my/13516/1/0001.pdf Tong, G.B. and Ab. Ghani, S.M. and Abdul Rahman, S. (2007) Crystallinity and Si-H bonding configuration of nc-Si:H films grown by Layer-by-layer (LBL) deposition technique at different RF power. In: International Workshop and Conference on Nanotechnology , 12-15 June 2007, Bangi, Malaysia. (Submitted)
spellingShingle T Technology (General)
Tong, G.B.
Ab. Ghani, S.M.
Abdul Rahman, S.
Crystallinity and Si-H bonding configuration of nc-Si:H films grown by Layer-by-layer (LBL) deposition technique at different RF power
title Crystallinity and Si-H bonding configuration of nc-Si:H films grown by Layer-by-layer (LBL) deposition technique at different RF power
title_full Crystallinity and Si-H bonding configuration of nc-Si:H films grown by Layer-by-layer (LBL) deposition technique at different RF power
title_fullStr Crystallinity and Si-H bonding configuration of nc-Si:H films grown by Layer-by-layer (LBL) deposition technique at different RF power
title_full_unstemmed Crystallinity and Si-H bonding configuration of nc-Si:H films grown by Layer-by-layer (LBL) deposition technique at different RF power
title_short Crystallinity and Si-H bonding configuration of nc-Si:H films grown by Layer-by-layer (LBL) deposition technique at different RF power
title_sort crystallinity and si h bonding configuration of nc si h films grown by layer by layer lbl deposition technique at different rf power
topic T Technology (General)
url http://eprints.um.edu.my/13516/1/0001.pdf
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AT abdulrahmans crystallinityandsihbondingconfigurationofncsihfilmsgrownbylayerbylayerlbldepositiontechniqueatdifferentrfpower