Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores
Reported herein are a pair of supramolecular pseudo-isomers, namely, (Cu 3I 3)(Cu 3L 3) 2· H 2O (1) and (Cu 3I 3)(Cu 3L 3) 2 (2) (L = 3-(4-pyridyl)-5-isobutyl-pyrazolate), both of which incorporate Cu 3Pz 3 (Pz = pyrazolate) and Cu 3I 3 clusters as luminophores. The two complexes show distinct yello...
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Format: | Article |
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Royal Society of Chemistry
2011
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