Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores
Reported herein are a pair of supramolecular pseudo-isomers, namely, (Cu 3I 3)(Cu 3L 3) 2· H 2O (1) and (Cu 3I 3)(Cu 3L 3) 2 (2) (L = 3-(4-pyridyl)-5-isobutyl-pyrazolate), both of which incorporate Cu 3Pz 3 (Pz = pyrazolate) and Cu 3I 3 clusters as luminophores. The two complexes show distinct yello...
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| Format: | Article |
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Royal Society of Chemistry
2011
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| _version_ | 1796961739914346496 |
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| author | Zhan, Shun-Ze Li, Mian Zhou, Xiao-Ping Li, Dan Ng, Seik Weng |
| author_facet | Zhan, Shun-Ze Li, Mian Zhou, Xiao-Ping Li, Dan Ng, Seik Weng |
| author_sort | Zhan, Shun-Ze |
| collection | UM |
| description | Reported herein are a pair of supramolecular pseudo-isomers, namely, (Cu 3I 3)(Cu 3L 3) 2· H 2O (1) and (Cu 3I 3)(Cu 3L 3) 2 (2) (L = 3-(4-pyridyl)-5-isobutyl-pyrazolate), both of which incorporate Cu 3Pz 3 (Pz = pyrazolate) and Cu 3I 3 clusters as luminophores. The two complexes show distinct yellow (570 nm) and orange (638 nm) emissions, which are ascribed to the formation of the excimer and exciplex involving the same or different copper(i)-cluster-based luminophores. © 2011 The Royal Society of Chemistry. |
| first_indexed | 2024-03-06T05:58:37Z |
| format | Article |
| id | um.eprints-23008 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:58:37Z |
| publishDate | 2011 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | um.eprints-230082019-11-14T07:55:33Z http://eprints.um.edu.my/23008/ Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores Zhan, Shun-Ze Li, Mian Zhou, Xiao-Ping Li, Dan Ng, Seik Weng Q Science (General) QD Chemistry Reported herein are a pair of supramolecular pseudo-isomers, namely, (Cu 3I 3)(Cu 3L 3) 2· H 2O (1) and (Cu 3I 3)(Cu 3L 3) 2 (2) (L = 3-(4-pyridyl)-5-isobutyl-pyrazolate), both of which incorporate Cu 3Pz 3 (Pz = pyrazolate) and Cu 3I 3 clusters as luminophores. The two complexes show distinct yellow (570 nm) and orange (638 nm) emissions, which are ascribed to the formation of the excimer and exciplex involving the same or different copper(i)-cluster-based luminophores. © 2011 The Royal Society of Chemistry. Royal Society of Chemistry 2011 Article PeerReviewed Zhan, Shun-Ze and Li, Mian and Zhou, Xiao-Ping and Li, Dan and Ng, Seik Weng (2011) Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores. RSC Advances, 1 (8). pp. 1457-1459. ISSN 2046-2069, DOI https://doi.org/10.1039/c1ra00566a <https://doi.org/10.1039/c1ra00566a>. https://doi.org/10.1039/c1ra00566a doi:10.1039/c1ra00566a |
| spellingShingle | Q Science (General) QD Chemistry Zhan, Shun-Ze Li, Mian Zhou, Xiao-Ping Li, Dan Ng, Seik Weng Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores |
| title | Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores |
| title_full | Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores |
| title_fullStr | Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores |
| title_full_unstemmed | Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores |
| title_short | Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores |
| title_sort | excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from cu3 pyrazolate 3 and cu3i3 coordination luminophores |
| topic | Q Science (General) QD Chemistry |
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