Polar effects in hydrogen abstraction from benzaldehydes—II : Radical chlorination by CCl3SO2Cl

The relative rates of chlorination of substituted benzaldehydes with CCl3SO2Cl (I) have been determined in dilute CCl4 solution at 80° by means of competitive reactions using p-diethylbenzene as reference standard. A polar effect (ρ{variant} = -0·54) correlated by the Hammett equation with the σ con...

Full description

Bibliographic Details
Main Author: Lee, Kheng H.
Format: Article
Published: Elsevier 1970
Subjects: