N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV)
The Sn-IV atom in the title compound, [Sn(C6H5)(2)(C18H11ClN2O3)], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C2SnNO2 trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)degrees]. The two phenyl rings are oriented at a dihedr...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5368/1/Lee-2009-N_%27-5-Chloro-2-oxido.pdf |
| _version_ | 1825719083721555968 |
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| author | Lee, S.M. Ng, S.W. Ali, Hapipah Mohd Lo, K.M. |
| author_facet | Lee, S.M. Ng, S.W. Ali, Hapipah Mohd Lo, K.M. |
| author_sort | Lee, S.M. |
| collection | UM |
| description | The Sn-IV atom in the title compound, [Sn(C6H5)(2)(C18H11ClN2O3)], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C2SnNO2 trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)degrees]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)degrees. Intramolecular O-H center dot center dot center dot N hydrogen bonding is present in the crystal structure. |
| first_indexed | 2024-03-06T05:14:14Z |
| format | Article |
| id | um.eprints-5368 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:14:14Z |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-53682019-01-31T04:37:12Z http://eprints.um.edu.my/5368/ N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV) Lee, S.M. Ng, S.W. Ali, Hapipah Mohd Lo, K.M. QD Chemistry The Sn-IV atom in the title compound, [Sn(C6H5)(2)(C18H11ClN2O3)], is O,N,O'-chelated by the deprotonated Schiff base ligand and further bonded by two phenyl rings in a distorted cis-C2SnNO2 trigonal-bipyramidal geometry [C-Sn-C = 125.7 (2)degrees]. The two phenyl rings are oriented at a dihedral angle of 55.2 (3)degrees. Intramolecular O-H center dot center dot center dot N hydrogen bonding is present in the crystal structure. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5368/1/Lee-2009-N_%27-5-Chloro-2-oxido.pdf Lee, S.M. and Ng, S.W. and Ali, Hapipah Mohd and Lo, K.M. (2009) N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 65. M1689-U1615. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536809050107 <https://doi.org/10.1107/s1600536809050107>. http://journals.iucr.org/e/issues/2009/12/00/xu2687/xu2687.pdf 10.1107/s1600536809050107 |
| spellingShingle | QD Chemistry Lee, S.M. Ng, S.W. Ali, Hapipah Mohd Lo, K.M. N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV) |
| title | N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV) |
| title_full | N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV) |
| title_fullStr | N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV) |
| title_full_unstemmed | N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV) |
| title_short | N '-5-Chloro-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 ',O-2 diphenyltin(IV) |
| title_sort | n 5 chloro 2 oxidobenzylidene kappa o 3 hydroxy 2 naphthohydrazidato kappa n 2 o 2 diphenyltin iv |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5368/1/Lee-2009-N_%27-5-Chloro-2-oxido.pdf |
| work_keys_str_mv | AT leesm n5chloro2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2o2diphenyltiniv AT ngsw n5chloro2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2o2diphenyltiniv AT alihapipahmohd n5chloro2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2o2diphenyltiniv AT lokm n5chloro2oxidobenzylidenekappao3hydroxy2naphthohydrazidatokappan2o2diphenyltiniv |