Randomness test of fatty acids distribution in triacylglycerol molecules of palm oil

For food purposes, the palm oil is generally fractionated to solid (stearin) and liquid (olein) fractions. Distribution of fatty acids in triacylglycerols of palm oil determines the fate of fractionation in terms of yield and quality of the products, specifically the liquid fraction or olein. The mo...

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Main Authors: Che Man, Yaakob, H. M. Salim, Tri Haryati, Mohd Ghazali, Hasanah, Buana, Lalang
Format: Article
Language:English
Published: Food & Nutrition Press 1998
Online Access:http://psasir.upm.edu.my/id/eprint/51306/1/51306.pdf
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author Che Man, Yaakob
H. M. Salim, Tri Haryati
Mohd Ghazali, Hasanah
Buana, Lalang
author_facet Che Man, Yaakob
H. M. Salim, Tri Haryati
Mohd Ghazali, Hasanah
Buana, Lalang
author_sort Che Man, Yaakob
collection UPM
description For food purposes, the palm oil is generally fractionated to solid (stearin) and liquid (olein) fractions. Distribution of fatty acids in triacylglycerols of palm oil determines the fate of fractionation in terms of yield and quality of the products, specifically the liquid fraction or olein. The more trisaturated and triunsaturated and the less mono- and disaturated will yield higher and better quality olein. There are six types of fatty acids found in the palm oil, but only 14 combinations are found in the triacylglycerols. In this study, such combinations were statistically tested to determine whether or not the fatty acids are randomly distributed, and if it was not, toward which direction the regulatory agent works. The distribution of fatty acids in the palm oil triacylglycerols was found to be nonrandomly distributed. Unfortunately, the palm tended to form 11.98% higher disaturated triacylglycerols, −7.4% less triunsaturated, and −4.25% less trisaturated compared to when the arrangement was random. If manipulation could be induced in such a way that the synthesis of triacylglycerols becomes random, the triunsaturated and trisaturated triacylglycerol proportion expectedly would increased to 12.57% and 12.43%, respectively. Such manipulation can be done in the plant through genetic engineering, or in the harvestedpuit through application of stimulant, or in the oil through chemical or enzymatic transesterification.
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spelling upm.eprints-513062017-07-04T03:26:37Z http://psasir.upm.edu.my/id/eprint/51306/ Randomness test of fatty acids distribution in triacylglycerol molecules of palm oil Che Man, Yaakob H. M. Salim, Tri Haryati Mohd Ghazali, Hasanah Buana, Lalang For food purposes, the palm oil is generally fractionated to solid (stearin) and liquid (olein) fractions. Distribution of fatty acids in triacylglycerols of palm oil determines the fate of fractionation in terms of yield and quality of the products, specifically the liquid fraction or olein. The more trisaturated and triunsaturated and the less mono- and disaturated will yield higher and better quality olein. There are six types of fatty acids found in the palm oil, but only 14 combinations are found in the triacylglycerols. In this study, such combinations were statistically tested to determine whether or not the fatty acids are randomly distributed, and if it was not, toward which direction the regulatory agent works. The distribution of fatty acids in the palm oil triacylglycerols was found to be nonrandomly distributed. Unfortunately, the palm tended to form 11.98% higher disaturated triacylglycerols, −7.4% less triunsaturated, and −4.25% less trisaturated compared to when the arrangement was random. If manipulation could be induced in such a way that the synthesis of triacylglycerols becomes random, the triunsaturated and trisaturated triacylglycerol proportion expectedly would increased to 12.57% and 12.43%, respectively. Such manipulation can be done in the plant through genetic engineering, or in the harvestedpuit through application of stimulant, or in the oil through chemical or enzymatic transesterification. Food & Nutrition Press 1998 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/51306/1/51306.pdf Che Man, Yaakob and H. M. Salim, Tri Haryati and Mohd Ghazali, Hasanah and Buana, Lalang (1998) Randomness test of fatty acids distribution in triacylglycerol molecules of palm oil. Journal of Food Lipids, 5 (2). pp. 113-123. ISSN 1065-7258; ESSN: 1745-4522 http://onlinelibrary.wiley.com/wol1/doi/10.1111/j.1745-4522.1998.tb00111.x/abstract 10.1111/j.1745-4522.1998.tb00111.x
spellingShingle Che Man, Yaakob
H. M. Salim, Tri Haryati
Mohd Ghazali, Hasanah
Buana, Lalang
Randomness test of fatty acids distribution in triacylglycerol molecules of palm oil
title Randomness test of fatty acids distribution in triacylglycerol molecules of palm oil
title_full Randomness test of fatty acids distribution in triacylglycerol molecules of palm oil
title_fullStr Randomness test of fatty acids distribution in triacylglycerol molecules of palm oil
title_full_unstemmed Randomness test of fatty acids distribution in triacylglycerol molecules of palm oil
title_short Randomness test of fatty acids distribution in triacylglycerol molecules of palm oil
title_sort randomness test of fatty acids distribution in triacylglycerol molecules of palm oil
url http://psasir.upm.edu.my/id/eprint/51306/1/51306.pdf
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