Thermogravimetric analysis of polyhydroxyalkanoates (PHA)/nano-calcium phosphate (nCaP)/chitosan biocomposite for heat-related manufacturing process

Nowadays, the adaptability of biodegradable Polyhydroxyalkanoates (PHA) polymer has been thoroughly assessed to its full potential including shape, mechanical characteristics, thermal properties and biocompatibility. Additionally, PHA has been produced as biomaterials with potential applications i...

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Main Authors: Mat Isa, Najah, Razak, Aisyah, Haiqal, Aiman, Adzila, Sharifah
Format: Conference or Workshop Item
Language:English
Published: 2024
Subjects:
Online Access:http://eprints.uthm.edu.my/11158/1/P16579_cd715f34de2f282de4fd07549d832a8d%207.pdf
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author Mat Isa, Najah
Razak, Aisyah
Haiqal, Aiman
Adzila, Sharifah
author_facet Mat Isa, Najah
Razak, Aisyah
Haiqal, Aiman
Adzila, Sharifah
author_sort Mat Isa, Najah
collection UTHM
description Nowadays, the adaptability of biodegradable Polyhydroxyalkanoates (PHA) polymer has been thoroughly assessed to its full potential including shape, mechanical characteristics, thermal properties and biocompatibility. Additionally, PHA has been produced as biomaterials with potential applications in bone regeneration. Similar to the mineral apatite found in human bones, nano calcium phosphates (nCaP) are minerals that are necessary for tissue development and cell adhesion, which have an impact on newly formed apatite. This study aims to investigate the influence of additives on thermal stability of biocomposite via thermogravimetric analysis (TGA) machine. PHA pellets were mixed with nCaP as filler ranging from 3-15wt% and 10wt% of chitosan binder via conventional melt compounding. Thermal analysis showed that the addition of bio-filler improves thermal stability of PHA with highest onset temperature recorded at 208.1°C. Morphological analysis showed that the addition of nCaP and chitosan alters the flow characteristics of the composite resulting in surface roughness. Subsequently, in order to prevent the biocomposite from decomposing, all heatrelated activities particularly those involving machining, it is recommended to perform at temperatures that do not exceed the onset temperature
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spelling uthm.eprints-111582024-06-11T02:56:41Z http://eprints.uthm.edu.my/11158/ Thermogravimetric analysis of polyhydroxyalkanoates (PHA)/nano-calcium phosphate (nCaP)/chitosan biocomposite for heat-related manufacturing process Mat Isa, Najah Razak, Aisyah Haiqal, Aiman Adzila, Sharifah T Technology (General) Nowadays, the adaptability of biodegradable Polyhydroxyalkanoates (PHA) polymer has been thoroughly assessed to its full potential including shape, mechanical characteristics, thermal properties and biocompatibility. Additionally, PHA has been produced as biomaterials with potential applications in bone regeneration. Similar to the mineral apatite found in human bones, nano calcium phosphates (nCaP) are minerals that are necessary for tissue development and cell adhesion, which have an impact on newly formed apatite. This study aims to investigate the influence of additives on thermal stability of biocomposite via thermogravimetric analysis (TGA) machine. PHA pellets were mixed with nCaP as filler ranging from 3-15wt% and 10wt% of chitosan binder via conventional melt compounding. Thermal analysis showed that the addition of bio-filler improves thermal stability of PHA with highest onset temperature recorded at 208.1°C. Morphological analysis showed that the addition of nCaP and chitosan alters the flow characteristics of the composite resulting in surface roughness. Subsequently, in order to prevent the biocomposite from decomposing, all heatrelated activities particularly those involving machining, it is recommended to perform at temperatures that do not exceed the onset temperature 2024-01-19 Conference or Workshop Item PeerReviewed text en http://eprints.uthm.edu.my/11158/1/P16579_cd715f34de2f282de4fd07549d832a8d%207.pdf Mat Isa, Najah and Razak, Aisyah and Haiqal, Aiman and Adzila, Sharifah (2024) Thermogravimetric analysis of polyhydroxyalkanoates (PHA)/nano-calcium phosphate (nCaP)/chitosan biocomposite for heat-related manufacturing process. In: AIP Conference Proceedings. https://doi.org/10.1063/5.0183247
spellingShingle T Technology (General)
Mat Isa, Najah
Razak, Aisyah
Haiqal, Aiman
Adzila, Sharifah
Thermogravimetric analysis of polyhydroxyalkanoates (PHA)/nano-calcium phosphate (nCaP)/chitosan biocomposite for heat-related manufacturing process
title Thermogravimetric analysis of polyhydroxyalkanoates (PHA)/nano-calcium phosphate (nCaP)/chitosan biocomposite for heat-related manufacturing process
title_full Thermogravimetric analysis of polyhydroxyalkanoates (PHA)/nano-calcium phosphate (nCaP)/chitosan biocomposite for heat-related manufacturing process
title_fullStr Thermogravimetric analysis of polyhydroxyalkanoates (PHA)/nano-calcium phosphate (nCaP)/chitosan biocomposite for heat-related manufacturing process
title_full_unstemmed Thermogravimetric analysis of polyhydroxyalkanoates (PHA)/nano-calcium phosphate (nCaP)/chitosan biocomposite for heat-related manufacturing process
title_short Thermogravimetric analysis of polyhydroxyalkanoates (PHA)/nano-calcium phosphate (nCaP)/chitosan biocomposite for heat-related manufacturing process
title_sort thermogravimetric analysis of polyhydroxyalkanoates pha nano calcium phosphate ncap chitosan biocomposite for heat related manufacturing process
topic T Technology (General)
url http://eprints.uthm.edu.my/11158/1/P16579_cd715f34de2f282de4fd07549d832a8d%207.pdf
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AT haiqalaiman thermogravimetricanalysisofpolyhydroxyalkanoatesphananocalciumphosphatencapchitosanbiocompositeforheatrelatedmanufacturingprocess
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