Effect of etching as pre-treatment for electroless copper plating on silicon wafer

Metallic coatings, such as copper films can be easily deposited on semiconductor materials like silicon wafer without prior surface pre-treatment using the electroless process. However, the adhesion of the copper film can be very weak and can easily peels off. In this study, the effect of etching in...

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Main Authors: Mior Shahidina, Shazatul Akmaliah, Fadila, Nor Akmal, Yusopa, Mohd Zamri, Tamina, Mohd Nasir, Osman, Saliza Azlina
Format: Article
Published: Penerbit UTM Press 2017
Subjects:
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author Mior Shahidina, Shazatul Akmaliah
Fadila, Nor Akmal
Yusopa, Mohd Zamri
Tamina, Mohd Nasir
Osman, Saliza Azlina
author_facet Mior Shahidina, Shazatul Akmaliah
Fadila, Nor Akmal
Yusopa, Mohd Zamri
Tamina, Mohd Nasir
Osman, Saliza Azlina
author_sort Mior Shahidina, Shazatul Akmaliah
collection UTHM
description Metallic coatings, such as copper films can be easily deposited on semiconductor materials like silicon wafer without prior surface pre-treatment using the electroless process. However, the adhesion of the copper film can be very weak and can easily peels off. In this study, the effect of etching in hydrofluoric acid solution as a surface pre-treatment prior to electroless plating on silicon wafer was studied. The etching time in hydrofluoric acid was varied at 1, 3 and 5 minutes in order to investigate the adhesion behaviour of the coating layer. The surface morphology of the electroless plated samples was observed using a field emission scanning electron microscope (FESEM) and the coating thickness was measured using cross sectional analysis. The results showed that longer etching time (5 minutes) produced thicker Cu deposits (8.5μm) than 1 minute etching time (5μm). In addition, by increasing the etching time, the mechanical bonding between the copper film and the substrate is improved.
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spelling uthm.eprints-56002022-01-17T01:57:02Z http://eprints.uthm.edu.my/5600/ Effect of etching as pre-treatment for electroless copper plating on silicon wafer Mior Shahidina, Shazatul Akmaliah Fadila, Nor Akmal Yusopa, Mohd Zamri Tamina, Mohd Nasir Osman, Saliza Azlina T Technology (General) TP155-156 Chemical engineering Metallic coatings, such as copper films can be easily deposited on semiconductor materials like silicon wafer without prior surface pre-treatment using the electroless process. However, the adhesion of the copper film can be very weak and can easily peels off. In this study, the effect of etching in hydrofluoric acid solution as a surface pre-treatment prior to electroless plating on silicon wafer was studied. The etching time in hydrofluoric acid was varied at 1, 3 and 5 minutes in order to investigate the adhesion behaviour of the coating layer. The surface morphology of the electroless plated samples was observed using a field emission scanning electron microscope (FESEM) and the coating thickness was measured using cross sectional analysis. The results showed that longer etching time (5 minutes) produced thicker Cu deposits (8.5μm) than 1 minute etching time (5μm). In addition, by increasing the etching time, the mechanical bonding between the copper film and the substrate is improved. Penerbit UTM Press 2017 Article PeerReviewed Mior Shahidina, Shazatul Akmaliah and Fadila, Nor Akmal and Yusopa, Mohd Zamri and Tamina, Mohd Nasir and Osman, Saliza Azlina (2017) Effect of etching as pre-treatment for electroless copper plating on silicon wafer. Jurnal Teknologi (Sciences & Engineering), 79 (7). pp. 61-69. ISSN 0127-9696
spellingShingle T Technology (General)
TP155-156 Chemical engineering
Mior Shahidina, Shazatul Akmaliah
Fadila, Nor Akmal
Yusopa, Mohd Zamri
Tamina, Mohd Nasir
Osman, Saliza Azlina
Effect of etching as pre-treatment for electroless copper plating on silicon wafer
title Effect of etching as pre-treatment for electroless copper plating on silicon wafer
title_full Effect of etching as pre-treatment for electroless copper plating on silicon wafer
title_fullStr Effect of etching as pre-treatment for electroless copper plating on silicon wafer
title_full_unstemmed Effect of etching as pre-treatment for electroless copper plating on silicon wafer
title_short Effect of etching as pre-treatment for electroless copper plating on silicon wafer
title_sort effect of etching as pre treatment for electroless copper plating on silicon wafer
topic T Technology (General)
TP155-156 Chemical engineering
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