Junction formation with HWCVD and TCAD model of an epitaxial back contact solar cell

In this paper, we present morphological and electrical characteristics of a junction formed of Si p-type films deposited on an n-type silicon wafer using a hot wire chemical vapor deposition (HWCVD) tool. We describe the fabrication process and study the influence of diborane flow and postprocess an...

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Main Authors: Rahman, T., Nawabjan, A., Tarazona, A., Bagnall, D. M., Boden, S. A.
Format: Article
Published: IEEE Electron Devices Society 2016
Subjects:
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author Rahman, T.
Nawabjan, A.
Tarazona, A.
Bagnall, D. M.
Boden, S. A.
author_facet Rahman, T.
Nawabjan, A.
Tarazona, A.
Bagnall, D. M.
Boden, S. A.
author_sort Rahman, T.
collection ePrints
description In this paper, we present morphological and electrical characteristics of a junction formed of Si p-type films deposited on an n-type silicon wafer using a hot wire chemical vapor deposition (HWCVD) tool. We describe the fabrication process and study the influence of diborane flow and postprocess annealing in improving junction characteristics. Our morphological studies undertaken using atomic force microscopy show that the initial deposition suffered from voids rather than being a uniform film; however, this improves significantly under our annealing treatment. The improvement in morphology was observed in the electrical characteristics, with estimated $V-{\text{oc}}$ doubling and rectification of the junction improving by several orders of magnitude. Fitting of the current-voltage curves to a two-diode model showed that increasing the diborane flow in the process helps reduce the saturation current and ideality factors, while increasing the shunt resistance. Electrochemical capacitance-voltage (ECV) and quasi-steady-state photoconductance measurements are used to characterize the deposited films further. A solar cell device with a silicon epitaxy emitter is modeled using industry-standard 3-D modeling tools and input parameters from experimental data, and the impact of defects is studied. A potential efficiency approaching 25% is shown to be feasible for an optimized device.
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spelling utm.eprints-717762017-11-15T03:08:37Z http://eprints.utm.my/71776/ Junction formation with HWCVD and TCAD model of an epitaxial back contact solar cell Rahman, T. Nawabjan, A. Tarazona, A. Bagnall, D. M. Boden, S. A. QA75 Electronic computers. Computer science In this paper, we present morphological and electrical characteristics of a junction formed of Si p-type films deposited on an n-type silicon wafer using a hot wire chemical vapor deposition (HWCVD) tool. We describe the fabrication process and study the influence of diborane flow and postprocess annealing in improving junction characteristics. Our morphological studies undertaken using atomic force microscopy show that the initial deposition suffered from voids rather than being a uniform film; however, this improves significantly under our annealing treatment. The improvement in morphology was observed in the electrical characteristics, with estimated $V-{\text{oc}}$ doubling and rectification of the junction improving by several orders of magnitude. Fitting of the current-voltage curves to a two-diode model showed that increasing the diborane flow in the process helps reduce the saturation current and ideality factors, while increasing the shunt resistance. Electrochemical capacitance-voltage (ECV) and quasi-steady-state photoconductance measurements are used to characterize the deposited films further. A solar cell device with a silicon epitaxy emitter is modeled using industry-standard 3-D modeling tools and input parameters from experimental data, and the impact of defects is studied. A potential efficiency approaching 25% is shown to be feasible for an optimized device. IEEE Electron Devices Society 2016 Article PeerReviewed Rahman, T. and Nawabjan, A. and Tarazona, A. and Bagnall, D. M. and Boden, S. A. (2016) Junction formation with HWCVD and TCAD model of an epitaxial back contact solar cell. IEEE Journal of Photovoltaics, 6 (6). pp. 1396-1402. ISSN 2156-3381 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84994765324&doi=10.1109%2fJPHOTOV.2016.2598277&partnerID=40&md5=00511d5cbd0c57b61972aa83d59db479
spellingShingle QA75 Electronic computers. Computer science
Rahman, T.
Nawabjan, A.
Tarazona, A.
Bagnall, D. M.
Boden, S. A.
Junction formation with HWCVD and TCAD model of an epitaxial back contact solar cell
title Junction formation with HWCVD and TCAD model of an epitaxial back contact solar cell
title_full Junction formation with HWCVD and TCAD model of an epitaxial back contact solar cell
title_fullStr Junction formation with HWCVD and TCAD model of an epitaxial back contact solar cell
title_full_unstemmed Junction formation with HWCVD and TCAD model of an epitaxial back contact solar cell
title_short Junction formation with HWCVD and TCAD model of an epitaxial back contact solar cell
title_sort junction formation with hwcvd and tcad model of an epitaxial back contact solar cell
topic QA75 Electronic computers. Computer science
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