Generation of Brönsted acidity in AlMCM-41 by sulphation for enhanced liquid phase tert-butylation of phenol

AlMCM-41 mesoporous molecular sieve modified by impregnation with sulphuric acid in toluene possesses only Brönsted acid sites. The catalyst exhibits a high catalytic activity for tert-butylation of phenol with high selectivity to 2,4-di-tert-butylphenol in liquid phase. 27Al MAS NMR study indicat...

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Bibliographic Details
Main Authors: Ng, Eng Poh, Nur, Hadi, Wong, Ka Lun, Muhid, Mohd Nazlan Mohd, Hamdan, Halimaton
Format: Article
Published: Elsevier B.V. 2007
Subjects: