Stereochemical aspects of nucleophilic addition reactions to alkoxycarbene cations of the iron chiral auxiliary [(eta(5)-C5H5)Fe(CO)(PPh3)]
Alkoxy carbene complexes incorporating the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)] were prepared in good yields from either the corresponding acyl complexes or methoxymethyl complex of the auxiliary. A range of nucleophilic addition reactions to these alkoxy carbene complexes showed moderate t...
| Principais autores: | , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado em: |
2013
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| Resumo: | Alkoxy carbene complexes incorporating the iron chiral auxiliary [(η5-C5H5)Fe(CO)(PPh3)] were prepared in good yields from either the corresponding acyl complexes or methoxymethyl complex of the auxiliary. A range of nucleophilic addition reactions to these alkoxy carbene complexes showed moderate to high diastereoselectivities and the reactive conformations of the carbene complexes under these conditions are discussed. © 2013 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. |
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