Porphyrin-polyyne [3] and [5]rotaxanes
Porphyrin–polyyne [3]- and [5]rotaxanes have been synthesized by condensing aldehyde–rotaxanes with pyrrole or dipyrromethane. The crystal structure of a [3]rotaxane shows that the macrocycles adopt compact conformations, holding the hexaynes near the porphyrin core, and that the phenanthroline unit...
| প্রধান লেখক: | , , , |
|---|---|
| বিন্যাস: | Journal article |
| প্রকাশিত: |
American Chemical Society
2017
|