Mechanistic investigation of Rh(i)-catalysedasymmetric Suzuki–Miyaura coupling withracemic allyl halides

Mechanistic investigation of Rh(i)-catalysedasymmetric Suzuki–Miyaura coupling withracemic allyl halides

Understanding how catalytic asymmetric reactions with racemic starting materials can operate would enable new enantioselective cross-coupling reactions that give chiral products. Here we propose a catalytic cycle for the highly enantioselective Rh(I)-catalysed Suzuki–Miyaura coupling of boronic acid...

Descrizione completa

Dettagli Bibliografici
Autori principali:	Van Dijk, LL, Ardkhean, R, Sidera, M, Karabiyikoglu, S, Sari, Ö, Claridge, T, Lloyd-Jones, G, Paton, R, Fletcher, S
Natura:	Journal article
Lingua:	English
Pubblicazione:	Nature 2021

Documenti analoghi

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
di: Schäfer, P, et al.
Pubblicazione: (2017)

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
di: Philipp Schäfer, et al.
Pubblicazione: (2017-06-01)

Correction: Author Correction: Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
di: Philipp Schäfer, et al.
Pubblicazione: (2018-05-01)

Asymmetric Suzuki-Miyaura couplings of acyclic allylic systems
di: Stojalnikova, V
Pubblicazione: (2023)

Chelation enables selectivity control in enantioconvergent Suzuki–Miyaura cross-couplings on acyclic allylic systems
di: Stojalnikova, V, et al.
Pubblicazione: (2024)

Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids
di: Sidera, M, et al.
Pubblicazione: (2015)

Mechanistic studies on a Cu-catalyzed asymmetric allylic al-kylation with cyclic racemic starting materials
di: Rideau, E, et al.
Pubblicazione: (2017)

Enantio- and diastereoselective Suzuki-Miyaura coupling with racemic bicycles
di: Goetzke, F, et al.
Pubblicazione: (2019)

An asymmetric Suzuki-Miyaura approach to prostaglandins: Synthesis of Tafluprost
di: Kučera, R, et al.
Pubblicazione: (2020)

Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides
di: Schafer, P, et al.
Pubblicazione: (2017)

Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides
di: Yang, Yang, et al.
Pubblicazione: (2015)

Palladium-mediated site-selective Suzuki-Miyaura protein modification at genetically encoded aryl halides.
di: Spicer, C, et al.
Pubblicazione: (2011)

Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling
di: Yuqiang Li, et al.
Pubblicazione: (2020-01-01)

Enantiomerically enriched tetrahydropyridine allyl chlorides
di: Karabiyikoglu, S, et al.
Pubblicazione: (2020)

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation
di: Billingsley, Kelvin L., et al.
Pubblicazione: (2015)

trans-Dichlorobis(XPhos)palladium(II) Precatalyst for Suzuki–Miyaura Cross-Coupling Reactions of Aryl/Vinyl Sulfonates/Halides: Scope, Mechanistic Study, and Synthetic Applications
di: Fatih Sirindil, et al.
Pubblicazione: (2021-12-01)

Application of the Suzuki-Miyaura Reaction in the Synthesis of Flavonoids
di: Fanie R. Van Heerden, et al.
Pubblicazione: (2013-04-01)

A Novel Graphene-Supported Palladium Catalyst for Suzuki–Miyaura Coupling of Less Reactive Heteroaryl Halides in Water
di: Abu, Taher, et al.
Pubblicazione: (2016)

Palladium(II)-catalyzed Suzuki–Miyaura Reactions of Arylboronic Acid with Aryl Halide in the Presence of Aryl-Ferrocenyl-Phosphines
di: A. T. Khabiyev, et al.
Pubblicazione: (2014-01-01)

A novel 4-aminoantipyrine-Pd(II) complex catalyzes Suzuki–Miyaura cross-coupling reactions of aryl halides
di: Claudia A. Contreras-Celedón, et al.
Pubblicazione: (2014-12-01)

Recent Developments in the Suzuki-Miyaura Reaction: 2010–2014
di: Irene Maluenda, et al.
Pubblicazione: (2015-04-01)

Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
di: Lin Guo, et al.
Pubblicazione: (2019-04-01)

Palladium-catalyzed Suzuki-Miyaura coupling of thioureas or thioamides
di: Shaoyu Mai, et al.
Pubblicazione: (2019-12-01)

Nickel-catalyzed Suzuki-Miyaura reactions of unactivated halides with alkyl boranes and planar-chiral borabenzene catalysts for Diels-Alder reactions
di: Lu, Zhe
Pubblicazione: (2011)

Hydrogenolysis of Allyl and Benzyl Halides and Related Compounds
di: Bissette, A, et al.
Pubblicazione: (2014)

Suzuki–Miyaura cross-coupling optimization enabled by automated feedback
di: Reizman, Brandon Jacob, et al.
Pubblicazione: (2017)

Rewriting the bacterial glycocalyx via Suzuki-Miyaura cross-coupling
di: Spicer, C, et al.
Pubblicazione: (2013)

Room-temperature Suzuki–Miyaura coupling of heteroaryl chlorides and tosylates
di: Yang, Junfeng, et al.
Pubblicazione: (2013)

Copper(I)-catalyzed sulfonylative Suzuki-Miyaura cross-coupling
di: Willis, M, et al.
Pubblicazione: (2017)

Cyclopalladated ferrocenylimines: highly active catalysts for Suzuki-Miyaura reaction
di: Yangjie Wu, et al.
Pubblicazione: (2004-10-01)

Peptide stapling by late-stage Suzuki–Miyaura cross-coupling
di: Hendrik Gruß, et al.
Pubblicazione: (2022-01-01)

Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides
di: González, J, et al.
Pubblicazione: (2019)

Self-liganded Suzuki-Miyaura coupling for site-selective protein PEGylation.
di: Dumas, A, et al.
Pubblicazione: (2013)

Rhodium-catalysed regio- and enantioselective Suzuki-Miyaura cross-coupling reactions
di: Liu, K
Pubblicazione: (2023)

Silica-coated magnetic palladium nanocatalyst for Suzuki-Miyaura cross-coupling
di: Md. Lutfor Rahman, et al.
Pubblicazione: (2022)

A convenient catalyst for aqueous and protein Suzuki-Miyaura cross-coupling.
di: Chalker, J, et al.
Pubblicazione: (2009)

New Tricyclic Aryl Quinazoline Derivatives by Suzuki‐Miyaura Cross‐Coupling
di: Burkhon Elmuradov, et al.
Pubblicazione: (2024-12-01)

Silica-coated magnetic palladium nanocatalyst for Suzuki-Miyaura cross-coupling
di: Md. Lutfor Rahman, et al.
Pubblicazione: (2022-08-01)

Suzuki-Miyaura Cross-Coupling in Acylation Reactions, Scope and Recent Developments
di: Annamaria Deagostino, et al.
Pubblicazione: (2013-01-01)

Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki–Miyaura Cross Coupling
di: Jamie M. Neely, et al.
Pubblicazione: (2016-12-01)