Mechanistic investigation of Rh(i)-catalysedasymmetric Suzuki–Miyaura coupling withracemic allyl halides

Mechanistic investigation of Rh(i)-catalysedasymmetric Suzuki–Miyaura coupling withracemic allyl halides

Understanding how catalytic asymmetric reactions with racemic starting materials can operate would enable new enantioselective cross-coupling reactions that give chiral products. Here we propose a catalytic cycle for the highly enantioselective Rh(I)-catalysed Suzuki–Miyaura coupling of boronic acid...

书目详细资料
Main Authors:	Van Dijk, LL, Ardkhean, R, Sidera, M, Karabiyikoglu, S, Sari, Ö, Claridge, T, Lloyd-Jones, G, Paton, R, Fletcher, S
格式:	Journal article
语言:	English
出版:	Nature 2021

相似书籍

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
由: Schäfer, P, et al.
出版: (2017)

Correction: Author Correction: Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
由: Philipp Schäfer, et al.
出版: (2018-05-01)

Asymmetric Suzuki-Miyaura couplings of acyclic allylic systems
由: Stojalnikova, V
出版: (2023)

Chelation enables selectivity control in enantioconvergent Suzuki–Miyaura cross-couplings on acyclic allylic systems
由: Stojalnikova, V, et al.
出版: (2024)

Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids
由: Sidera, M, et al.
出版: (2015)

Mechanistic studies on a Cu-catalyzed asymmetric allylic al-kylation with cyclic racemic starting materials
由: Rideau, E, et al.
出版: (2017)

Enantio- and diastereoselective Suzuki-Miyaura coupling with racemic bicycles
由: Goetzke, F, et al.
出版: (2019)

An asymmetric Suzuki-Miyaura approach to prostaglandins: Synthesis of Tafluprost
由: Kučera, R, et al.
出版: (2020)

Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides
由: Schafer, P, et al.
出版: (2017)

Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides
由: Yang, Yang, et al.
出版: (2015)

Palladium-mediated site-selective Suzuki-Miyaura protein modification at genetically encoded aryl halides.
由: Spicer, C, et al.
出版: (2011)

Enantiomerically enriched tetrahydropyridine allyl chlorides
由: Karabiyikoglu, S, et al.
出版: (2020)

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation
由: Billingsley, Kelvin L., et al.
出版: (2015)

Application of the Suzuki-Miyaura Reaction in the Synthesis of Flavonoids
由: Fanie R. Van Heerden, et al.
出版: (2013-04-01)

A Novel Graphene-Supported Palladium Catalyst for Suzuki–Miyaura Coupling of Less Reactive Heteroaryl Halides in Water
由: Abu, Taher, et al.
出版: (2016)

A novel 4-aminoantipyrine-Pd(II) complex catalyzes Suzuki–Miyaura cross-coupling reactions of aryl halides
由: Claudia A. Contreras-Celedón, et al.
出版: (2014-12-01)

Recent Developments in the Suzuki-Miyaura Reaction: 2010–2014
由: Irene Maluenda, et al.
出版: (2015-04-01)

Nickel-catalyzed Suzuki-Miyaura reactions of unactivated halides with alkyl boranes and planar-chiral borabenzene catalysts for Diels-Alder reactions
由: Lu, Zhe
出版: (2011)

Hydrogenolysis of Allyl and Benzyl Halides and Related Compounds
由: Bissette, A, et al.
出版: (2014)

Suzuki–Miyaura cross-coupling optimization enabled by automated feedback
由: Reizman, Brandon Jacob, et al.
出版: (2017)

Rewriting the bacterial glycocalyx via Suzuki-Miyaura cross-coupling
由: Spicer, C, et al.
出版: (2013)

Room-temperature Suzuki–Miyaura coupling of heteroaryl chlorides and tosylates
由: Yang, Junfeng, et al.
出版: (2013)

Copper(I)-catalyzed sulfonylative Suzuki-Miyaura cross-coupling
由: Willis, M, et al.
出版: (2017)

Cyclopalladated ferrocenylimines: highly active catalysts for Suzuki-Miyaura reaction
由: Yangjie Wu, et al.
出版: (2004-10-01)

Peptide stapling by late-stage Suzuki–Miyaura cross-coupling
由: Hendrik Gruß, et al.
出版: (2022-01-01)

Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides
由: González, J, et al.
出版: (2019)

Self-liganded Suzuki-Miyaura coupling for site-selective protein PEGylation.
由: Dumas, A, et al.
出版: (2013)

Rhodium-catalysed regio- and enantioselective Suzuki-Miyaura cross-coupling reactions
由: Liu, K
出版: (2023)

Silica-coated magnetic palladium nanocatalyst for Suzuki-Miyaura cross-coupling
由: Md. Lutfor Rahman, et al.
出版: (2022)

A convenient catalyst for aqueous and protein Suzuki-Miyaura cross-coupling.
由: Chalker, J, et al.
出版: (2009)

New Tricyclic Aryl Quinazoline Derivatives by Suzuki‐Miyaura Cross‐Coupling
由: Burkhon Elmuradov, et al.
出版: (2024-12-01)

Silica-coated magnetic palladium nanocatalyst for Suzuki-Miyaura cross-coupling
由: Md. Lutfor Rahman, et al.
出版: (2022-08-01)

Suzuki-Miyaura Cross-Coupling in Acylation Reactions, Scope and Recent Developments
由: Annamaria Deagostino, et al.
出版: (2013-01-01)

Insight into Transmetalation Enables Cobalt-Catalyzed Suzuki–Miyaura Cross Coupling
由: Jamie M. Neely, et al.
出版: (2016-12-01)

Highly enantioselective hiyama cross-coupling via Rh-catalyzed allylic arylation of racemic allyl chlorides
由: Fletcher, S
出版: (2019)

Bismuth-mediated diastereoselective allylation reaction of carbonyl compounds with cyclic allylic halides or cinnamyl halide
由: Liu, Xuan-Yu, et al.
出版: (2021)

Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides.
由: Sidera, M, et al.
出版: (2015)

Suzuki–Miyaura Cross-Coupling for the Synthesis of Key Intermediates of Ketoprofen and Bifonazole Analogues
由: Nayane Abreu do Amaral e Silva, et al.
出版: (2023-11-01)

Light‐Enhanced Suzuki–Miyaura Crosscoupling Reaction by Polyoxopalladates Clusters: Doping Effect
由: Huiyong Li, et al.
出版: (2024-12-01)

A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water
由: Aires da Conceição Silva, et al.
出版: (2013-01-01)