One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.
Dicarbonyl-stabilised diazo functionality is tolerated during alkene cross-metathesis using Grubbs' catalyst, but undergoes subsequent tandem carbonyl ylide formation-intramolecular 1,3-dipolar cycloaddition on addition of catalytic Rh2(OAc)4 in a one-pot operation.
Main Authors: | , , |
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Format: | Journal article |
Language: | English |
Published: |
2006
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_version_ | 1797087844307566592 |
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author | Hodgson, D Angrish, D Labande, A |
author_facet | Hodgson, D Angrish, D Labande, A |
author_sort | Hodgson, D |
collection | OXFORD |
description | Dicarbonyl-stabilised diazo functionality is tolerated during alkene cross-metathesis using Grubbs' catalyst, but undergoes subsequent tandem carbonyl ylide formation-intramolecular 1,3-dipolar cycloaddition on addition of catalytic Rh2(OAc)4 in a one-pot operation. |
first_indexed | 2024-03-07T02:41:24Z |
format | Journal article |
id | oxford-uuid:aa931daa-f426-452a-bc48-426d47ca441c |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T02:41:24Z |
publishDate | 2006 |
record_format | dspace |
spelling | oxford-uuid:aa931daa-f426-452a-bc48-426d47ca441c2022-03-27T03:16:04ZOne-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:aa931daa-f426-452a-bc48-426d47ca441cEnglishSymplectic Elements at Oxford2006Hodgson, DAngrish, DLabande, ADicarbonyl-stabilised diazo functionality is tolerated during alkene cross-metathesis using Grubbs' catalyst, but undergoes subsequent tandem carbonyl ylide formation-intramolecular 1,3-dipolar cycloaddition on addition of catalytic Rh2(OAc)4 in a one-pot operation. |
spellingShingle | Hodgson, D Angrish, D Labande, A One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester. |
title | One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester. |
title_full | One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester. |
title_fullStr | One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester. |
title_full_unstemmed | One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester. |
title_short | One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester. |
title_sort | one pot cross metathesis tandem carbonyl ylide formation intramolecular cycloaddition of an unsaturated 2 diazo 3 6 diketoester |
work_keys_str_mv | AT hodgsond onepotcrossmetathesistandemcarbonylylideformationintramolecularcycloadditionofanunsaturated2diazo36diketoester AT angrishd onepotcrossmetathesistandemcarbonylylideformationintramolecularcycloadditionofanunsaturated2diazo36diketoester AT labandea onepotcrossmetathesistandemcarbonylylideformationintramolecularcycloadditionofanunsaturated2diazo36diketoester |