One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.

Dicarbonyl-stabilised diazo functionality is tolerated during alkene cross-metathesis using Grubbs' catalyst, but undergoes subsequent tandem carbonyl ylide formation-intramolecular 1,3-dipolar cycloaddition on addition of catalytic Rh2(OAc)4 in a one-pot operation.

Bibliographic Details
Main Authors: Hodgson, D, Angrish, D, Labande, A
Format: Journal article
Language:English
Published: 2006
_version_ 1797087844307566592
author Hodgson, D
Angrish, D
Labande, A
author_facet Hodgson, D
Angrish, D
Labande, A
author_sort Hodgson, D
collection OXFORD
description Dicarbonyl-stabilised diazo functionality is tolerated during alkene cross-metathesis using Grubbs' catalyst, but undergoes subsequent tandem carbonyl ylide formation-intramolecular 1,3-dipolar cycloaddition on addition of catalytic Rh2(OAc)4 in a one-pot operation.
first_indexed 2024-03-07T02:41:24Z
format Journal article
id oxford-uuid:aa931daa-f426-452a-bc48-426d47ca441c
institution University of Oxford
language English
last_indexed 2024-03-07T02:41:24Z
publishDate 2006
record_format dspace
spelling oxford-uuid:aa931daa-f426-452a-bc48-426d47ca441c2022-03-27T03:16:04ZOne-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:aa931daa-f426-452a-bc48-426d47ca441cEnglishSymplectic Elements at Oxford2006Hodgson, DAngrish, DLabande, ADicarbonyl-stabilised diazo functionality is tolerated during alkene cross-metathesis using Grubbs' catalyst, but undergoes subsequent tandem carbonyl ylide formation-intramolecular 1,3-dipolar cycloaddition on addition of catalytic Rh2(OAc)4 in a one-pot operation.
spellingShingle Hodgson, D
Angrish, D
Labande, A
One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.
title One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.
title_full One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.
title_fullStr One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.
title_full_unstemmed One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.
title_short One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.
title_sort one pot cross metathesis tandem carbonyl ylide formation intramolecular cycloaddition of an unsaturated 2 diazo 3 6 diketoester
work_keys_str_mv AT hodgsond onepotcrossmetathesistandemcarbonylylideformationintramolecularcycloadditionofanunsaturated2diazo36diketoester
AT angrishd onepotcrossmetathesistandemcarbonylylideformationintramolecularcycloadditionofanunsaturated2diazo36diketoester
AT labandea onepotcrossmetathesistandemcarbonylylideformationintramolecularcycloadditionofanunsaturated2diazo36diketoester