Fusion and planarization of a quinoidal porphyrin dimer.
The crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the pi-system and reduces the optical HOMO-LUMO gap while increasing the gap between the first...
| मुख्य लेखकों: | , , , |
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| स्वरूप: | Journal article |
| भाषा: | English |
| प्रकाशित: |
2002
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| सारांश: | The crystal structure, near-infrared spectrum and electrochemistry of a quinoidal triply-linked porphyrin dimer are compared with those of its singly-linked precursor; fusing the two porphyrins planarizes the pi-system and reduces the optical HOMO-LUMO gap while increasing the gap between the first oxidation and reduction potentials. |
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