A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H.
The solid-state structure of the rhodium complex (dimethylamine-dimethylaminoborane-borane-κ(2)H,H')dihydridobis(triisopropylphosphane-κP)rhodium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, [RhH(2)(C(4)H(18)B(2)N(2))(C(9)H(21)P)(2)](C(32)H(12)BF(24)), is reported. The complex contains...
| Κύριοι συγγραφείς: | , |
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| Μορφή: | Journal article |
| Γλώσσα: | English |
| Έκδοση: |
2011
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| _version_ | 1826296690243534848 |
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| author | Chaplin, AB Weller, A |
| author_facet | Chaplin, AB Weller, A |
| author_sort | Chaplin, AB |
| collection | OXFORD |
| description | The solid-state structure of the rhodium complex (dimethylamine-dimethylaminoborane-borane-κ(2)H,H')dihydridobis(triisopropylphosphane-κP)rhodium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, [RhH(2)(C(4)H(18)B(2)N(2))(C(9)H(21)P)(2)](C(32)H(12)BF(24)), is reported. The complex contains the linear diborazine H(3)B·NMe(2)BH(2)·NMe(2)H, a kinetically important intermediate in the transition-metal-mediated dehydrocoupling of H(3)B·NMe(2)H, ultimately affording the dimeric amino-borane [H(2)BNMe(2)](2). The structure of the title complex contains a distorted octahedral Rh(III) centre, with mutually trans phosphane ligands and cis hydride ligands. The diborazine is bound through two Rh-H-B σ-bonds and exhibits a gauche conformation with respect to the B-N-B-N backbone. |
| first_indexed | 2024-03-07T04:20:14Z |
| format | Journal article |
| id | oxford-uuid:cac54d7b-5f99-4a68-98fa-b09ceb1ceda7 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T04:20:14Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:cac54d7b-5f99-4a68-98fa-b09ceb1ceda72022-03-27T07:09:46ZA rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:cac54d7b-5f99-4a68-98fa-b09ceb1ceda7EnglishSymplectic Elements at Oxford2011Chaplin, ABWeller, AThe solid-state structure of the rhodium complex (dimethylamine-dimethylaminoborane-borane-κ(2)H,H')dihydridobis(triisopropylphosphane-κP)rhodium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, [RhH(2)(C(4)H(18)B(2)N(2))(C(9)H(21)P)(2)](C(32)H(12)BF(24)), is reported. The complex contains the linear diborazine H(3)B·NMe(2)BH(2)·NMe(2)H, a kinetically important intermediate in the transition-metal-mediated dehydrocoupling of H(3)B·NMe(2)H, ultimately affording the dimeric amino-borane [H(2)BNMe(2)](2). The structure of the title complex contains a distorted octahedral Rh(III) centre, with mutually trans phosphane ligands and cis hydride ligands. The diborazine is bound through two Rh-H-B σ-bonds and exhibits a gauche conformation with respect to the B-N-B-N backbone. |
| spellingShingle | Chaplin, AB Weller, A A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H. |
| title | A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H. |
| title_full | A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H. |
| title_fullStr | A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H. |
| title_full_unstemmed | A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H. |
| title_short | A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H. |
| title_sort | rhodium iii complex of the linear diborazine h3b·nme2bh2·nme2h an intermediate in the dehydrocoupling of h3b·nme2h |
| work_keys_str_mv | AT chaplinab arhodiumiiicomplexofthelineardiborazineh3bnme2bh2nme2hanintermediateinthedehydrocouplingofh3bnme2h AT wellera arhodiumiiicomplexofthelineardiborazineh3bnme2bh2nme2hanintermediateinthedehydrocouplingofh3bnme2h AT chaplinab rhodiumiiicomplexofthelineardiborazineh3bnme2bh2nme2hanintermediateinthedehydrocouplingofh3bnme2h AT wellera rhodiumiiicomplexofthelineardiborazineh3bnme2bh2nme2hanintermediateinthedehydrocouplingofh3bnme2h |