The role of halogenated carborane monoanions in olefin hydrogenation catalysed by cationic iridium phosphine complexes.
Iridium hydridophosphine complexes of general formula [Ir(PR3)2H2(anion)](PR3= PPh3, PMe2Ph; anion =[1-closo-CB(11)H(6)Cl(6)]-, [1-closo-CB(11)H(6)I(6)]-, [BAr(F)4]-) have been prepared by hydrogenation of cyclooctadiene precursor complexes. Solid-state structures of selected examples of these compl...
المؤلفون الرئيسيون: | Moxham, G, Douglas, T, Brayshaw, S, Kociok-Köhn, G, Lowe, J, Weller, A |
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التنسيق: | Journal article |
اللغة: | English |
منشور في: |
2006
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مواد مشابهة
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Cationic rhodium mono-phosphine fragments partnered with carborane monoanions [closo-CB11H6X6]- (X = H, Br). Synthesis, structures and reactivity with alkenes.
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B-C activation in highly alkylated carborane monoanions partnered with cationic transition metal fragments: observations and comments
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Silver-phosphine complexes of the highly methylated carborane monoanion [closo-1-H-CB11Me11]-.
حسب: Clarke, A, وآخرون
منشور في: (2004) -
Sequential dehydrogenative borylation/hydrogenation route to polyethyl-substituted, weakly coordinating carborane anions
حسب: Molinos, E, وآخرون
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Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine).
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منشور في: (2008)