Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II)
In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N',N ''-tridentate chelating agent, making two five-membered rings with the Zn-II ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry....
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/5236/1/Hisham-2011-Dichlorido%7B2-morphol.pdf |
| _version_ | 1825719059866451968 |
|---|---|
| author | Hisham, N.A.I. Gwaram, N.S. Khaledi, H. Ali, Hapipah Mohd |
| author_facet | Hisham, N.A.I. Gwaram, N.S. Khaledi, H. Ali, Hapipah Mohd |
| author_sort | Hisham, N.A.I. |
| collection | UM |
| description | In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N',N ''-tridentate chelating agent, making two five-membered rings with the Zn-II ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intramolecular C-H center dot center dot center dot Cl interaction occurs. In the crystal, adjacent molecules are linked together via C-H center dot center dot center dot Cl hydrogen-bonding and long range C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions into a three-dimensional network. |
| first_indexed | 2024-03-06T05:13:52Z |
| format | Article |
| id | um.eprints-5236 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:13:52Z |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-52362019-01-30T00:57:43Z http://eprints.um.edu.my/5236/ Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II) Hisham, N.A.I. Gwaram, N.S. Khaledi, H. Ali, Hapipah Mohd QD Chemistry In the title compound, [ZnCl2(C13H19N3O)], the Schiff base ligand acts as an N,N',N ''-tridentate chelating agent, making two five-membered rings with the Zn-II ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intramolecular C-H center dot center dot center dot Cl interaction occurs. In the crystal, adjacent molecules are linked together via C-H center dot center dot center dot Cl hydrogen-bonding and long range C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions into a three-dimensional network. International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://eprints.um.edu.my/5236/1/Hisham-2011-Dichlorido%7B2-morphol.pdf Hisham, N.A.I. and Gwaram, N.S. and Khaledi, H. and Ali, Hapipah Mohd (2011) Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II). Acta Crystallographica Section E: Structure Reports Online, E67. m55. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810050671 <https://doi.org/10.1107/s1600536810050671>. http://journals.iucr.org/e/issues/2011/01/00/pv2366/index.html http://dx.doi.org/10.1107/s1600536810050671 |
| spellingShingle | QD Chemistry Hisham, N.A.I. Gwaram, N.S. Khaledi, H. Ali, Hapipah Mohd Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II) |
| title | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II) |
| title_full | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II) |
| title_fullStr | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II) |
| title_full_unstemmed | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II) |
| title_short | Dichlorido{2-morpholino-N- 1-(2-pyridyl)ethylidene ethanamine-kappa N-3,N ',N ''}zinc(II) |
| title_sort | dichlorido 2 morpholino n 1 2 pyridyl ethylidene ethanamine kappa n 3 n n zinc ii |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/5236/1/Hisham-2011-Dichlorido%7B2-morphol.pdf |
| work_keys_str_mv | AT hishamnai dichlorido2morpholinon12pyridylethylideneethanaminekappan3nnzincii AT gwaramns dichlorido2morpholinon12pyridylethylideneethanaminekappan3nnzincii AT khaledih dichlorido2morpholinon12pyridylethylideneethanaminekappan3nnzincii AT alihapipahmohd dichlorido2morpholinon12pyridylethylideneethanaminekappan3nnzincii |