Novel Route to Cationic Palladium(II)–Cyclopentadienyl Complexes Containing Phosphine Ligands and Their Catalytic Activities

Novel Route to Cationic Palladium(II)–Cyclopentadienyl Complexes Containing Phosphine Ligands and Their Catalytic Activities

The Pd(II) complexes [Pd(Cp)(L)<sub>n</sub>]<sub>m</sub>[BF<sub>4</sub>]<sub>m</sub> were synthesized via the reaction of cationic acetylacetonate complexes with cyclopentadiene in the presence of BF<sub>3</sub>∙OEt<sub>2</sub>...

Full description

Bibliographic Details
Main Authors:	Dmitry S. Suslov, Mikhail V. Bykov, Marina V. Pakhomova, Timur S. Orlov, Zorikto D. Abramov, Anastasia V. Suchkova, Igor A. Ushakov, Pavel A. Abramov, Alexander S. Novikov
Format:	Article
Language:	English
Published:	MDPI AG 2023-05-01
Series:	Molecules
Subjects:	palladium cyclopentadienyl acetylacetonate 1,3-butadiene telomerization phenylacetylene
Online Access:	https://www.mdpi.com/1420-3049/28/10/4141

Similar Items

Phosphine Functionalized Cp<sup>C</sup> Ligands and Their Metal Complexes
by: Florian Nährig, et al.
Published: (2023-04-01)

Ruthenium–Cyclopentadienyl–Cycloparaphenylene Complexes: Sizable Multicharged Cations Exhibiting High DNA-Binding Affinity and Remarkable Cytotoxicity
by: Konstantinos Ypsilantis, et al.
Published: (2024-01-01)

Singlet/Triplet State Anti/Aromaticity of CyclopentadienylCation: Sensitivity to Substituent Effect
by: Milovan Stojanović, et al.
Published: (2021-07-01)

Chiral Cyclopentadienyl Ruthenium Complexes as Versatile Catalysts for Enantioselective Transformations
by: David Kossler, et al.
Published: (2017-04-01)

Design and Anticancer Properties of New Water-Soluble Ruthenium–Cyclopentadienyl Complexes
by: Tânia S. Morais, et al.
Published: (2022-07-01)

Pd Catalysts Supported on Mixed Iron and Titanium Oxides in Phenylacetylene Hydrogenation: Effect of TiO<sub>2</sub> Content in Magnetic Support Material
by: Eldar T. Talgatov, et al.
Published: (2024-08-01)

Competing Metal–Ligand Interactions in Tris(cyclopentadienyl)-cyclohexylisonitrile Complexes of Trivalent Actinides and Lanthanides
by: Attila Kovács, et al.
Published: (2022-06-01)

Crystal structure of (1,3-di-tert-butyl-η5-cyclopentadienyl)trimethylhafnium(IV)
by: Adrián Pérez-Redondo, et al.
Published: (2015-05-01)

Heteronuclear Fe-Mn Cyclopentadienyl Complexes Supported on Boehmite. Thermochemistry and Thermodynamics of their Decomposition
by: A.I. Rustamova, et al.
Published: (2024-10-01)

Two-Step Spin Crossover and Contact-Tunable Giant Magnetoresistance in Cyclopentadienyl Metalloporphyrin
by: Mingbo Yu, et al.
Published: (2024-04-01)

Reaction of cyclopentadienyl and methyl radicals
by: Vladislav S. Krasnoukhov, et al.
Published: (2017-03-01)

Hypergolic Materials Synthesis through Reaction of Fuming Nitric Acid with Certain Cyclopentadienyl Compounds
by: Nikolaos Chalmpes, et al.
Published: (2020-10-01)

New Ruthenium-Cyclopentadienyl Complexes Affect Colorectal Cancer Hallmarks Showing High Therapeutic Potential
by: Ana Rita Brás, et al.
Published: (2023-06-01)

Macroporous Poly(hydromethylsiloxane) Networks as Precursors to Hybrid Ceramics (Ceramers) for Deposition of Palladium Catalysts
by: Jan Mrówka, et al.
Published: (2024-08-01)

trans-Acetyldicarbonyl(η5-cyclopentadienyl)[tris(3,5-dimethylphenyl)phosphane-κP]molybdenum(II)
by: Matthew T. Whited, et al.
Published: (2017-01-01)

Estudo de alguns compostos organolantanídeos: [LnCp2Cl.PPh3]
by: Gatti Paula M., et al.
Published: (2000-01-01)

Synthesis and Characterization of Ruthenium-Paraphenylene-Cyclopentadienyl Full-Sandwich Complexes: Cytotoxic Activity against A549 Lung Cancer Cell Line and DNA Binding Properties
by: Evangelia Sifnaiou, et al.
Published: (2023-12-01)

Isomerisation reaction of 1-heptene using complexes of ruthenium and palladium with phosphine and ligands : a comparison study /
by: 604303 Rusmidah Ali, et al.

Preparation and Investigation of Pd and Bimetallic Pd-Sn Nanocrystals on γ-Al<sub>2</sub>O<sub>3</sub>
by: Ivan Bondarchuk, et al.
Published: (2021-04-01)

A New Family of Iron(II)-Cyclopentadienyl Compounds Shows Strong Activity against Colorectal and Triple Negative Breast Cancer Cells
by: Adhan Pilon, et al.
Published: (2020-03-01)

Hydrotrifluoromethylation of Styrene and Phenylacetylene Derivatives under Visible-Light Photoredox Conditions
by: Amel Souibgui, et al.
Published: (2022-09-01)

Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols
by: Anthony Fers-Lidou, et al.
Published: (2016-09-01)

Heck Transformations of Biological Compounds Catalyzed by Phosphine-Free Palladium
by: Stanisława Tarnowicz-Ligus, et al.
Published: (2018-09-01)

A novel combinatory treatment against a CDDP-resistant non-small cell lung cancer based on a Ruthenium(II)-cyclopentadienyl compound
by: Iris C. Salaroglio, et al.
Published: (2024-10-01)

The organic chemistry of palladium/
by: Maitlis, Peter M
Published: (1971)

Palladium-Catalyzed Cross-Coupling Reaction of Bis(cyclopentadienyl)diaryltitaniums with Terminal Alkynes
by: Yuki Murata, et al.
Published: (2023-10-01)

Dynamics of Pd Subsurface Hydride Formation and Their Impact on the Selectivity Control for Selective Butadiene Hydrogenation Reaction
by: Esther Asedegbega-Nieto, et al.
Published: (2023-03-01)

Establishment of Cysteine Detection Method in Food Based on Fluorescent Probe
by: Rui HAN, et al.
Published: (2022-02-01)

The oxidative coupling between benzaldehyde derivatives and phenylacetylene catalyzed by rhodium complexes via C-H bond activation
by: Zhao Xinyi, et al.
Published: (2020-03-01)

Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles
by: Seah, Jeffrey Wee Kiong, et al.
Published: (2022)

Cardiotoxicity of palladium compounds
by: Perić Tanja S., et al.
Published: (2013-01-01)

Tuning the helical sense and elongation of polymers through the combined action of the two components of tetraalkylammonium-anion salts
by: Seila Leiras, et al.
Published: (2021-08-01)

Improving the reactivity of phenylacetylene macrocycles toward topochemical polymerization by side chains modification
by: Simon Rondeau-Gagné, et al.
Published: (2014-07-01)

Evaluation of palladium substitutes for gold /
by: 187107 Graham, A. H., et al.

Electrodeposition and market effects of palladium and its alloys /
by: 201306 Baker, R. G., et al.

Palladium - nickel oxide based catalyst for carbon dioxide methanation reaction /
by: Khairunnisa Abdul Latiff, 1987-, et al.
Published: (2009)

Tetramethylcyclopentadienyl Samarium(II) Metallocene Chemistry: Isolation of a Bimetallic Sm(II)/Sm(II) Complex
by: Joseph Q. Nguyen, et al.
Published: (2022-12-01)

A study of ammoniacal palladium-nickel bath /
by: 198815 Reid, Jonathan D., et al.

Some features of concentration oscillations in the phenylacetylene oxidative carbonylation reaction
by: S. N. Gorodsky, et al.
Published: (2010-10-01)

Synthesis and Characterization of Copper Impregnated Mesoporous Carbon as Heterogeneous Catalyst for Phenylacetylene Carboxylation with Carbon Dioxide
by: Putri Nurul Amalia, et al.
Published: (2020-12-01)