The C-4 stereochemistry of leucocyanidin substrates for anthocyanidin synthase affects product selectivity.

Anthocyanidin synthase (ANS), an iron(II) and 2-oxoglutarate (2OG) dependent oxygenase, catalyses the penultimate step in anthocyanin biosynthesis by oxidation of the 2R,3S,4S-cis-leucoanthocyanidins. It has been believed that in vivo the products of ANS are the anthocyanidins. However, in vitro stu...

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Main Authors: Turnbull, J, Nagle, M, Seibel, J, Welford, R, Grant, G, Schofield, C
格式: Journal article
语言:English
出版: 2003